[(2,6-iPr₂C₆H₃)NC(Me)C(Me)NH(2,6-iPr2C₆H₃)AlMe₂] | 1424662-19-0

• 英文名称: [(2,6-iPr₂C₆H₃)NC(Me)C(Me)NH(2,6-iPr2C₆H₃)AlMe₂]
• CAS: 1424662-19-0
• 化学式: C₃₀H₄₇AlN₂
• 分子量: 462.698
• InChiKey: NUQRCEHVKLIWRI-FAIYXUOWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-N,3-N-bis[2,6-di(propan-2-yl)phenyl]but-2-ene-2,3-diamine 、 三甲基铝 以 正己烷 、 甲苯 为溶剂， 反应 6.0h， 以67%的产率得到[(2,6-iPr₂C₆H₃)NC(Me)C(Me)NH(2,6-iPr2C₆H₃)AlMe₂]
  参考文献：
  名称：

  Synthesis and Reactions of a Redox-Active α-Diimine Aluminum Complex

  摘要：

  The reaction of the ene-diamine LH2 (L = [ArNC(Me)C(Me)NAr](2-), Ar = 2,6-iPr(2)C(6)H(3)) with AlMe3 and AlEt3 yielded the aluminum dimethyl complex (LH)AlMe2 (1) and the radical (L-center dot)AlEt2 (2; L-center dot = [ArNC(Me)C(Me)-NAr](center dot-)), respectively. Treatment of 2 with O-2 and TEMPO (2,2,6,6-tetramethylpiperidin-l-oxyl) led to hydrogen abstraction from the methyl group at the ligand backbone to give the diamagnetic species (L*)AlEt2 (3; L* = [ArN= C(Me)C(CH2)NAr](-)) and (L*)Al(TEMPO)(Et) (4). In contrast, the reaction of 2 with iodine resulted in the iodination of the Al-C bonds and yielded the radical (L-center dot)AlI2 (5). Reaction of 2 with BCl3 led to electron transfer between the alpha-diimine radicals with the formation of the aluminum cation [(L-0)AlCl2](+)[AlCl4](-) (6; L-0 = ArN=C(Me)(Me)C=NAr) and the diazaborole LBCl (7). The structures of compounds 2, 3, and 7 have been determined by X-ray single-crystal diffraction, and the paramagnetic species 2 has been characterized by EPR measurements.

  DOI：

  10.1021/om300920y