1-ferrocenyl-3-ruthenocenyl-2-propen-1-one | 79643-37-1

• 英文名称: 1-ferrocenyl-3-ruthenocenyl-2-propen-1-one
• 英文别名: 3-ferrocenyl-1-ruthenocenyl-2-propen-1-one
• CAS: 79643-37-1；79354-76-0
• 化学式: C₂₃H₂₀FeORu
• 分子量: 469.328
• InChiKey: NVWZJWGZSBVXLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二茂铁甲醛 、 acetylruthenocene 在 乙醇 、 sodium 作用下， 以 乙醇 为溶剂， 以70%的产率得到1-ferrocenyl-3-ruthenocenyl-2-propen-1-one
  参考文献：
  名称：

  Synthesis of [3.3](1,1′)- and [5.5](1,1′)Ruthenocenophanes and Their Ferrocenoruthenocenophane Homologs

  摘要：

  通过分子间碱催化缩合反应，合成了[3.3](1,1′)钌吩烷-2,14-二烯-1,16-二酮、[5.5](1,1′)钌吩烷-2,14,17,29-四烯-1,16-二酮及其二茂铁钌吩烷同系物。

  DOI：

  10.1246/bcsj.54.2079

文献信息

• Ferrocene- and ruthenocene-containing chalcones: A spectroscopic and electrochemical study
  作者：Elizabeth Erasmus

  DOI：10.1016/j.ica.2011.08.024

  日期：2011.11

  Chalcones of the type Mc-CO-CH=CH-Ph, Ph-CO-CH=CH-Mc and Mc-CO-CH=CH-Mc with Mc = Fc = ferrocenyl or Rc = ruthenocenyl, and Ph = phenyl were synthesized. Synthesis was achieved by base catalyzed Claisen-Schmidt condensation of the appropriated acetyl and aldehyde in ethanol. Cyclic voltammetry in CH3CN in the presence of 0.1 moldm (3) [N(Bu)(4)][PF6] revealed chemical and electrochemical reversible behaviour for the Fc/Fc(+) couple and irreversible electrochemistry for the two electron Rc/Rc(2+) couple. The potential ranges for the Fc/Fc(+) couple varied in the range 138 <= E-o' <= 302 mV while E-pa for Rc/Rc(2+) couple was between 358 and 510 mV vs. FcH/FcH(+), the internal standard. Chalcones with the carbonyl group adjacent to the metallocene, are more difficult to oxidize. (C) 2011 Elsevier B.V. All rights reserved.