| 610269-60-8

• CAS: 610269-60-8
• 化学式: C₈₂H₉₀N₈O₂Zn₂
• 分子量: 1350.45
• InChiKey: PDXPWFQOAYSIJH-BNPYPBGKSA-N

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking:  Remarkable Thermal Behavior in a Solid

  摘要：

  On heating, syn-diporphyrin zinc complexes fused with bis(ethano)dimethoxyanthracene, the crystal structure of which showed a unique trimeric assembly, extruded one ethylene molecule at 240-310 degrees C to give a porphyrin-naphthoporphyrin diad, and the second retro-Diels-Alder reaction and concomitant decomposition of the methoxy groups occurred at 280-350 degrees C to give the anthraquinone-fused diporphyrin, while the first thermal conversion of the anti-diporphyrin zinc complex occurred in a much lower temperature range (180-230 degrees C).

  DOI：

  10.1021/ja036203f
• 作为产物：
  描述：

  以 二苯醚 为溶剂， 生成
  参考文献：
  名称：

  Hexagonal Columnar Porphyrin Assembly by Unique Trimeric Complexation of a Porphyrin Dimer with π−π Stacking:  Remarkable Thermal Behavior in a Solid

  摘要：

  On heating, syn-diporphyrin zinc complexes fused with bis(ethano)dimethoxyanthracene, the crystal structure of which showed a unique trimeric assembly, extruded one ethylene molecule at 240-310 degrees C to give a porphyrin-naphthoporphyrin diad, and the second retro-Diels-Alder reaction and concomitant decomposition of the methoxy groups occurred at 280-350 degrees C to give the anthraquinone-fused diporphyrin, while the first thermal conversion of the anti-diporphyrin zinc complex occurred in a much lower temperature range (180-230 degrees C).

  DOI：

  10.1021/ja036203f