名称:
Synthesis and structure of the cobalt(II) coordination compounds with N,N-dimethyl-N′,N′-dimethylthiocarbamoylsulfenamide
摘要:
The CoLX2 complexes were obtained by the reaction of N,N-dimethyl-N',N'-dimethylthio-carbamoylsulfenamide (L) with CoX2 (X = Cl, Br, I, NCS). The complexes were investigated by elemental and X-ray analysis, IR, H-1 NMR, and electron spectroscopy, conductometry, magnetochemistry, thermogravimetry. It is found that these compounds are high-spin complexes of pseudotetraedral structure with bidentate coordination of L through the thione sulfur atom and sulfenamide nitrogen atom.