Co(N,N-dimethyl-N',N'-dimethylthiocarbamoylsulfenamide)Cl2 | 1314519-17-9

• 英文名称: Co(N,N-dimethyl-N',N'-dimethylthiocarbamoylsulfenamide)Cl2
• CAS: 1314519-17-9
• 化学式: C₅H₁₂Cl₂CoN₂S₂
• 分子量: 294.195
• InChiKey: JXXCLQYIRUHEIJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Co(N,N-dimethyl-N',N'-dimethylthiocarbamoylsulfenamide)Cl2 以 neat (no solvent) 为溶剂， 生成 cobalt(II,III) oxide
  参考文献：
  名称：

  Synthesis and structure of the cobalt(II) coordination compounds with N,N-dimethyl-N′,N′-dimethylthiocarbamoylsulfenamide

  摘要：

  The CoLX2 complexes were obtained by the reaction of N,N-dimethyl-N',N'-dimethylthio-carbamoylsulfenamide (L) with CoX2 (X = Cl, Br, I, NCS). The complexes were investigated by elemental and X-ray analysis, IR, H-1 NMR, and electron spectroscopy, conductometry, magnetochemistry, thermogravimetry. It is found that these compounds are high-spin complexes of pseudotetraedral structure with bidentate coordination of L through the thione sulfur atom and sulfenamide nitrogen atom.

  DOI：

  10.1134/s1070363211050070
• 作为产物：
  描述：

  S-(N,N-dimethylthiocarbamoyl)-N,N-dimethylthiohydroxylamine 、 cobalt(II) chloride 以 乙醚 为溶剂， 生成 Co(N,N-dimethyl-N',N'-dimethylthiocarbamoylsulfenamide)Cl2
  参考文献：
  名称：

  Synthesis and structure of the cobalt(II) coordination compounds with N,N-dimethyl-N′,N′-dimethylthiocarbamoylsulfenamide

  摘要：

  The CoLX2 complexes were obtained by the reaction of N,N-dimethyl-N',N'-dimethylthio-carbamoylsulfenamide (L) with CoX2 (X = Cl, Br, I, NCS). The complexes were investigated by elemental and X-ray analysis, IR, H-1 NMR, and electron spectroscopy, conductometry, magnetochemistry, thermogravimetry. It is found that these compounds are high-spin complexes of pseudotetraedral structure with bidentate coordination of L through the thione sulfur atom and sulfenamide nitrogen atom.

  DOI：

  10.1134/s1070363211050070