copper(II)Br4(4,6-bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine) | 1073937-80-0

• 英文名称: copper(II)Br4(4,6-bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine)
• CAS: 1073937-80-0
• 化学式: C₁₄H₁₆Br₄Cu₂N₆
• 分子量: 715.029
• InChiKey: PQQMKACFYJFWFP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,6-bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine 、 copper(ll) bromide 以 乙醇 为溶剂， 以96%的产率得到copper(II)Br4(4,6-bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine)
  参考文献：
  名称：

  Cu(II) complexes with 4,6-bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and catalytic activity in ethylene polymerization reaction

  摘要：

  The Cu(II) complexes with 4,6-bis(3,5-dimethyl-]H-pyrazole-1-yl)pyrimidine (0) and 4-(3,5-di dimethyl-1H-pyrazole-1-y1)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine (L-2) of the composition (CuLBr4)-Br-1 and Cu-2,L(2)A(4) (A = Cl, Br), respectively, were synthesized and studied by IR and magnetochemical methods. The molecular structure of the complexes is likely to be binuclear. In the presence of cocatalysts methylaluminoxane and triisobutylaluminium, the title complexes exhibit catalytic activity in the ethylene polymerization reaction.

  DOI：

  10.1134/s107032840708009x