| 852414-63-2

• CAS: 852414-63-2
• 化学式: C₁₄H₁₂I₂Mo
• 分子量: 529.998
• InChiKey: SULZMEANBHDYRL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 四丁基碘化铵 以 二氯甲烷 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and reactivity of mixed-ring indenyl complexes of molybdenocene

  摘要：

  The complex [IndCpMo(NCMe)(2)][BF4](2) provides a suitable entry to the synthesis of IndCpMoBr(2) and IndCpMoMe(2). The latter, also available from IndCpMoX(2) (X = Cl, Br) and MeMgCl, reacts with HCl to give IndCpMoCI(Me) which, in turn reacts with NaSPh to yield IndCpMo(SPh)(Me). Cyclic voltammetry shows that these three alkyl complexes undergo a le reversible oxidation to 17 e Mo-V cations. IndCpMoCl(Me) is oxidized by [Cp2Fe]BF4 to afford [IndCpMoCl(Me)]BF4 in 95% yield. Reaction of [IndCpMo(NCMe)(2)][BF4](2) with KBPz(4) in CH2Cl2/NMF leads to [IndCpMo(kappa(2) -BPz(4))]BF4. Taken together with previous reports these results show that the indenyl ring slows down substitutional chemistry at the Cp'Mo-2(IV) fragment (Cp' = Cp, Ind) by steric reasons, overshadowing any acceleration due to a possible indenyl effect. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.01.027