[(HC(C(^tBu)NC₆H₃(iPr)₂)₂)Ni(diethyl ether)] | 1397866-52-2

• 英文名称: [(HC(C(^tBu)NC₆H₃(iPr)₂)₂)Ni(diethyl ether)]
• CAS: 1397866-52-2
• 化学式: C₄₁H₅₈N₄Ni
• 分子量: 665.628
• InChiKey: KPEZLOLABXVKLQ-WOSDKRSLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(HC(C(^tBu)NC₆H₃(iPr)₂)₂)Ni(η²-phenylhydrazido(1-))] 在 偶氮二甲酸二异丙酯 作用下， 以 乙腈 为溶剂， 反应 16.0h， 以64%的产率得到[(HC(C(^tBu)NC₆H₃(iPr)₂)₂)Ni(diethyl ether)]
  参考文献：
  名称：

  Reductive Deprotonation and Dehydrogenation of Phenylhydrazine at a Nickel Center To Give a Nickel Diazenido Complex

  摘要：

  The reaction of [(LNi)-Ni-tBu(OEt2)] (where L-tBu = [HC((CNC6H3)-N-tBu(Pr-i(2))(2)](-)) with phenylhydrazine leads to the phenylhydrazido(1-) complex [(LNi)-Ni-tBu(eta(2)-NPhNH2)] (1) with concomitant formation of H-2. Treatment of 1 with potassium graphite in the presence of crown ether again leads to H-2 evolution and affords the heterobimetallic complex [(LNi)-Ni-tBu(mu-eta(2):eta(2)-NPhNH))K(18-crown-6) containing the doubly deprotonated phenylhydrazido(2-) ligand. 1 can be converted into a phenyldiazenido complex [(LNi)-Ni-tBu(eta(1)-NNPh)] in the course of a dehydrogenation reaction employing 1,2-diisopropylazo dicarboxylate (DIAD) as the oxidant.

  DOI：

  10.1021/ic301066x