| 1008126-25-7

• CAS: 1008126-25-7
• 化学式: C₂₂H₁₈Cl₂CoN₄
• 分子量: 468.311
• InChiKey: KBAXXOPMXCXHOB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(1-isopropyl-1H-benzimidazol-2-yl)-1,10-phenanthroline 、 cobalt(II) chloride 以 乙醇 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  2-(Benzimidazol-2-yl)-1,10-phenanthrolyl metal (Fe and Co) complexes and their catalytic behaviors toward ethylene oligomerization

  摘要：

  The N boolean AND N boolean AND N-tridentatc metal complexes, LMCl2 (M = Fe or Co; L represents a ligand of 2-(benzimidazol-2-yl)-l, 10-phenanthrolines), were synthesized and fully characterized with spectroscopic and elemental analysis. The single-crystal X-ray crystallographic analyses revealed complex 1a with a distorted octahedron geometry due to incorporating one methanol molecule, and complexes 5a and 9b with a distorted trigonal-bipyramidal geometry. Upon activation with modified methylaluminoxane (MMAO), these complexes showed good to high catalytic activities toward ethylene oligomerization. The detailed investigations were carried out to disclose the influences of various reaction conditions and nature of ligands on their performing activities of metal complexes. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.11.020