[Ru(2,2'-bipyridine)2Lb]PF6∘C2H5OH | 1552308-42-5

• 英文名称: [Ru(2,2'-bipyridine)2Lb]PF6∘C2H5OH
• 英文别名: [Ru(2,2'-bipyridine)₂L_b]PF₆∘C₂H₅OH；[Ru(bpy)₂L_b]PF₆∘C₂H₅OH
• CAS: 1552308-42-5
• 化学式: C₂H₆O*C₃₇H₃₁N₅O₃Ru*F₆P
• 分子量: 885.788
• InChiKey: OKBMBBZRTQQEQU-FFPHMWHISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 乙醇 、 顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 以 水 为溶剂， 反应 4.5h， 以23%的产率得到[Ru(2,2'-bipyridine)2Lb]PF6∘C2H5OH
  参考文献：
  名称：

  A ruthenium(II) complex having a ligand undergoing partial C=N cleavage and unusual double-bond shift and nonchirality

  摘要：

  A novel six-coordinate ruthenium(II) complex 1, formulated as [Ru(bpy)(2)L-b]PF6 center dot C2H5OH (bpy = 2,2'-bipyridine), has been obtained and characterized. Ligand L-b in 1 comes from a chiral bis-Schiff-base ligand L-a which is condensed between sodium(l) salt of D- or L-phenylanine and terephthaldicarboxaldehyde. It is noted that ligand L-a undergoes partial C = N bond cleavage of Schiff-base unit forming a free aldehyde group at one end of phenyl ring, and an unusual proton migration, a C N double-bond shift and subsequent nonchirality at the other end simultaneously in the presence of a ruthenium(II) ion. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.11.046