| 1415567-65-5

• CAS: 1415567-65-5
• 化学式: C₂₉H₁₄ClN₄O₃ReS₂
• 分子量: 752.247
• InChiKey: XDMJVGKOZAHKTM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  五羰基氯铼(I) 、 2,9-di(benzo[d]thiazol-2-yl)-1,10-phenanthroline 以 甲苯 为溶剂， 以66%的产率得到
  参考文献：
  名称：

  Rhenium(I) tricarbonyl complexes with multidentate nitrogen-donor derivatives

  摘要：

  The reaction of [Re(CO)(5)X] (X = Cl, Br) with a series of six potentially multidentate nitrogen donor ligands (L1-L6) was studied. The ligands L1-L5 are coordinated bidentately in the neutral complexes of the type fac-[Re(CO)(3)X(L)] (1-5). The complex salt [Re(CO)(3)(L6)]Br (6) was formed by the reaction of [Re(CO)(5)Br] with 2-aminobenzaldehyde (aba), in which the tridentate ligand L6 was formed by the Schiff base condensation of three aba molecules. The crystal structures for complexes 1-6 were determined by X-ray single crystal diffraction. UV-Vis absorption spectra of the complexes show the intraligand and MLCT transitions. Electrochemical behaviour of the complexes was studied with cyclic voltammetry. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.078