fac-(Me3P)3IrCl3·MeCN | 1430817-85-8

• 英文名称: fac-(Me3P)3IrCl3·MeCN
• 英文别名: fac-[iridium(III)trichloride(tris(trimethylphosphine))] acetonitrile monosolvate
• CAS: 1430817-85-8
• 化学式: C₂H₃N*C₉H₂₇Cl₃IrP₃
• 分子量: 567.866
• InChiKey: ZCANZKVAJPXCCX-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  [iridium(III)(COD)(tris(trimethylphosphine))]*2HCl2(1-) 、 乙腈 生成 fac-(Me3P)3IrCl3·MeCN
  参考文献：
  名称：

  Synthesis, reactivity and crystal structures of various solvates of fac-tris(trimethylphosphine)trichloroiridium

  摘要：

  The synthesis of fac-tris(trimethylphosphine)iridiumtrichloride is reported and the crystal structure of five different solvates of this compound are analyzed. Compared with the idealized structure calculated with DFT methods, bond angles and distances differ considerably for all of the solvates examined. The utility of fac-tris(trimethylphosphine)iridiumtrichloride for the synthesis of organometallic compounds of iridium(III) is also demonstrated. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.02.021