tetra-n-butylammonium bis(benzohydroxymato)borate | 494754-18-6

• 英文名称: tetra-n-butylammonium bis(benzohydroxymato)borate
• CAS: 494754-18-6
• 化学式: C₁₄H₁₀BN₂O₄*C₁₆H₃₆N
• 分子量: 523.524
• InChiKey: GQNZSYADLRAATG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯甲羟肟酸 、 四丁基溴化铵 、 硼酸 在 Ag₂O 作用下， 以 苯 为溶剂， 以90%的产率得到tetra-n-butylammonium bis(benzohydroxymato)borate
  参考文献：
  名称：

  Hydroximato complexes of boron—the X-ray crystal structures of dicyclohexylammonium bis(benzohydroximato)borate chloroform solvate and tetra-n-propylammonium bis(benzohydroximato)borate

  摘要：

  Four new alkylammonium bis(benzohydroximato)borates have been prepared and characterized by elemental analysis, IR and H-1 NMR spectra. The crystal and molecular structures of dicycohexylammonium bis(benzohydroximato)borate chloroform solvate (1.CHCl3) and tetra-n-propylammonium bis(benzohydroximato)borate (3) have been determined by X-ray diffraction methods. In both examples the bis(hydroximato)borate anions show the expected spirochelate structure with slightly distorted tetrahedral BO4 coordination. The C-N as well as the C-O bonds within the chelate rings have considerable double bond character. Bond lengths and angles of the BONCO heterocyle are in good agreement with those observed in N-methylacetohydroxamatoboron complexes (Can. J. Chem. 55 (1977) 1, Can. J. Chem. 56 (1978) 1676). In the crystal structure of 1.CHCl3 the bis(benzoydroximato)borate anions are linked to the dicyclohexylammonium cations by strong N-H...O and N-H..N hydrogen bonds. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01187-7