[2-(2'-oxyphenyl)-1,3-bis[4-(2-oxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine](μ-methoxide)bis(azide)dicobalt(III) | 1109292-10-5

• 英文名称: [2-(2'-oxyphenyl)-1,3-bis[4-(2-oxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine](μ-methoxide)bis(azide)dicobalt(III)
• CAS: 1109292-10-5
• 化学式: C₂₈H₃₀Co₂N₁₀O₄
• 分子量: 688.597
• InChiKey: BWLJBNWZSBCMHM-TZRDZTCESA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 cobalt(II) diacetate tetrahydrate 、 2-(2'-hydroxyphenyl)-1,3-bis(2-(salicylideneamino)ethyl)diazolidine 、 sodium azide 在 air 作用下， 以 甲醇 为溶剂， 以75%的产率得到[2-(2'-oxyphenyl)-1,3-bis[4-(2-oxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine](μ-methoxide)bis(azide)dicobalt(III)
  参考文献：
  名称：

  [(Tmp)Co ₂ L] Complexes through Preassembly on 2,6‐Diformyl‐ and 2,6‐Bis(benzylimino)‐4‐methylphenolate Templates

  摘要：

  AbstractThe reaction of the dinucleating ligand H3L {2‐(2′‐hydroxyphenyl)‐1,3‐bis[4‐(2‐hydroxyphenyl)‐3‐azabut‐3‐enyl]‐1,3‐imidazolidine} with Co(OAc)2·4H2O and NaN3 in MeOH produces the methoxide‐bridged dicobalt complex [CoIII2(μ‐OMe)L(N3)2] (1) under aerobic conditions. If the reaction occurs in the presence of either 2,6‐diformyl‐4‐methylphenolate (dfp–) or 2,6‐bis(benzyliminomethyl)‐4‐methylphenolate (bip–), a preassembly of the [CoII2(OPh)]3+ units takes place on these templates before coordination with L3– in [CoII2(μ‐dfp)L]·3H2O (2·3H2O) and [CoII2(μ‐bip)L]·3H2O (3·3H2O), respectively. Incorporation of these coligands into the structure leads to stabilization of 3+ and 2+ oxidation states of the cobalt. In complex 2, the CoII ions are engaged in a weak antiferromagnetic interaction. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

  DOI：

  10.1002/ejic.200700551