3-bicymantrenylcarbinol | 193225-94-4

• 英文名称: 3-bicymantrenylcarbinol
• CAS: 193225-94-4
• 化学式: C₁₇H₁₀Mn₂O₇
• 分子量: 436.138
• InChiKey: WOFFUNMEGJHOJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  3-bicymantrenylcarbinol 在 Et₃SiH 、 CF₃COOH 作用下， 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Bicymantrenyl chemistry

  摘要：

  Planar chiral 2- and 3-bicymantrenylcarbaldehydes can be resolved to enantiomers through Schiff's bases with (S)-(-)-alpha-phenylethylamine. Optically active derivatives of bicymantrenyl with Me and CH2OH substituents were synthesized from (-)-3-bicymantrenylcarbaldehyde. The absolute configuration. of Schiff's base obtained from (+)-3-bicymantrenylcarbaldehyde was determined by X-ray diffraction analysis.

  DOI：

  10.1007/bf02495365
• 作为产物：
  描述：

  3-bicymantrenylaldehyde 在 NaBH₄ 作用下， 以 乙醇 为溶剂， 以91%的产率得到3-bicymantrenylcarbinol
  参考文献：
  名称：

  Bicymantrenyl chemistry

  摘要：

  Planar chiral 2- and 3-bicymantrenylcarbaldehydes can be resolved to enantiomers through Schiff's bases with (S)-(-)-alpha-phenylethylamine. Optically active derivatives of bicymantrenyl with Me and CH2OH substituents were synthesized from (-)-3-bicymantrenylcarbaldehyde. The absolute configuration. of Schiff's base obtained from (+)-3-bicymantrenylcarbaldehyde was determined by X-ray diffraction analysis.

  DOI：

  10.1007/bf02495365

文献信息

• Metallation of bicymantrenyl and synthesis of polycymantrenyls
  作者：A.G. Ginzburg、S.V. Suprunovich、F.M. Dolgushin、A.I. Yanovsky、E.V. Vorontsov、V.I. Sokolov

  DOI：10.1016/s0022-328x(96)06556-4

  日期：1997.5

  Bicymantrenyl, eta(5),eta(5)-C10H8[Mn(CO)(3)](2) (1), may be metallated at the Cp-ring with BuLi (THF, -60 degrees C) to give monolithium (2) and polylithium derivatives. Metallation of 1 proceeds concurrently on both alpha- and beta- positions, the beta-substitution product being predominant. A number of derivatives of 1 with substituents R = D, COOH, CHO, PPh2 have been synthesized in the reactions of monolithium derivative 2 with different electrophiles (D2O, CO2, DMFA, Ph2PCl respectively). Under the action of CuCl2 the oxidative coupling of 2 proceeds to give tetracymantrenyl (11a). Oxidative coupling of a mixture of 2 with cymantrenyllithium affords two isomers of tricymantrenyl (12a, 12b). The structures of 11a, 12a, 12b were established by an X-ray study. (C) 1997 Elsevier Science S.A.