[ruthenium(II)(η6-C6Me6)Cl2(κ1-P-2-diphenylphosphinobenzaldehyde)] | 686353-42-4

• 英文名称: [ruthenium(II)(η6-C6Me6)Cl2(κ1-P-2-diphenylphosphinobenzaldehyde)]
• CAS: 686353-42-4
• 化学式: C₃₁H₃₃Cl₂OPRu
• 分子量: 624.552
• InChiKey: WZWDEBQATQGUQA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  silver hexafluoroantimonate 、 [ruthenium(II)(η6-C6Me6)Cl2(κ1-P-2-diphenylphosphinobenzaldehyde)] 以 二氯甲烷 为溶剂， 以86%的产率得到[ruthenium(II)(η6-C6Me6)Cl(κ2-P,O-2-diphenylphosphinobenzaldehyde)][SbF6]
  参考文献：
  名称：

  Ruthenium(II) complexes containing 2-diphenylphosphinobenzaldehyde: synthesis and catalytic activity in transfer hydrogenation§

  摘要：

  The reaction of dimers [Ru(eta(6)-arene)(mu-Cl)Cl](2) (arene = C6H6 (2a); 1-Pr-i-4-C6H4Me (2b) 1,2,4,5-C6H2Me4 (2c); C6Me6 (2d)) with 2-diphenylphosphinobenzaidehyde (1) yields the neutral complexes [Ru(eta(6)-arene)Cl-2(kappa(1)-P-2-Ph2PC6H4CH=O)] (3a-d). Treatment of compounds 3a-d with one equivalent of AgSbF6 leads to the formation of the monocationic derivatives [Ru(eta(6)-arene)Cl(kappa(2)-P,O-2-Ph2PC6H4CH=O)][SbF6] (4a-d). When 3a-d are treated of AgSbF6 in presence of acetone, the dicationic complexes [Ru(eta(6)-arene)(kappa(1)-O-Me2C=O)(kappa(2)-P,O-2-Ph2PC6H4CH=O)][SbF6](2) (arene=C6H6 (5a); 1-Pr-i-4-C6H4Me (5b); 1,2,4,5-C6H2Me4 (5c), C6Me6 (5d)) are obtained, Complexes 3-5a-d have proven to be active catalysts in transfer hydrogenation of acetophenone by propan-2-ol. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00404-3
• 作为产物：
  描述：

  [RuCl2(hexamethylbenzene)]2 、 2-二苯基膦苯甲醛 以 二氯甲烷 为溶剂， 以79%的产率得到[ruthenium(II)(η6-C6Me6)Cl2(κ1-P-2-diphenylphosphinobenzaldehyde)]
  参考文献：
  名称：

  Ruthenium(II) complexes containing 2-diphenylphosphinobenzaldehyde: synthesis and catalytic activity in transfer hydrogenation§

  摘要：

  The reaction of dimers [Ru(eta(6)-arene)(mu-Cl)Cl](2) (arene = C6H6 (2a); 1-Pr-i-4-C6H4Me (2b) 1,2,4,5-C6H2Me4 (2c); C6Me6 (2d)) with 2-diphenylphosphinobenzaidehyde (1) yields the neutral complexes [Ru(eta(6)-arene)Cl-2(kappa(1)-P-2-Ph2PC6H4CH=O)] (3a-d). Treatment of compounds 3a-d with one equivalent of AgSbF6 leads to the formation of the monocationic derivatives [Ru(eta(6)-arene)Cl(kappa(2)-P,O-2-Ph2PC6H4CH=O)][SbF6] (4a-d). When 3a-d are treated of AgSbF6 in presence of acetone, the dicationic complexes [Ru(eta(6)-arene)(kappa(1)-O-Me2C=O)(kappa(2)-P,O-2-Ph2PC6H4CH=O)][SbF6](2) (arene=C6H6 (5a); 1-Pr-i-4-C6H4Me (5b); 1,2,4,5-C6H2Me4 (5c), C6Me6 (5d)) are obtained, Complexes 3-5a-d have proven to be active catalysts in transfer hydrogenation of acetophenone by propan-2-ol. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00404-3