[Hg2(μ-Cl)2Cl2(μ-η**(1)-N,N'-bis(acetylacetone)-1R,2R-diaminocyclohexane)]n | 1309861-02-6

• 英文名称: [Hg2(μ-Cl)2Cl2(μ-η**(1)-N,N'-bis(acetylacetone)-1R,2R-diaminocyclohexane)]n
• CAS: 1309861-02-6
• 化学式: C₁₆H₂₆Cl₄Hg₂N₂O₂
• 分子量: 821.387
• InChiKey: RRNIRSBWUDOKDH-JQKDLOGESA-J

反应信息

• 作为产物：
  描述：

  Bis-(acetylaceton)-(+)-1,2-diiminocyclohexan 、 mercury dichloride 以 乙醇 为溶剂， 以62%的产率得到[Hg2(μ-Cl)2Cl2(μ-η**(1)-N,N'-bis(acetylacetone)-1R,2R-diaminocyclohexane)]n
  参考文献：
  名称：

  Silver(I) and mercury(II) complexes with N,N′-bis(acetylacetone)-1R,2R-diaminocyclohexane ligands exhibiting three different coordination modes

  摘要：

  Treatment of AgNO3 with one equiv. of N, N'-bis(acetylacetone)-1R, 2R-diaminocyclohexane (L) afforded a mononuclear complex [Ag(eta(2)-L)NO3] (1) in which the central silver(I) atom adopts a distorted trigonal planar geometry by coordinating two carbon atoms of the methane moieties of the ligand and one oxygen atom of the NO3- group. Interaction of CF3COOAg with one equiv. of L produced a one-dimensional coordination polymer [Ag-2(mu-L)(CF3CO2)(2)](n) (2). Each silver(I) in 2 exhibits highly distorted square planar coordination geometry that connects one oxygen atom of L and one neighboring Ag atom with the Ag center dot center dot center dot Ag interactions. Reaction of HgCl2 with one equiv. of L resulted in the formation of one-dimensional [{Hg(mu-Cl)Cl}(2)(mu-eta(1)-L)](n) (3) with a C-coordinated dinuclear mercury(II) chloride moiety being linked by L. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.12.006