[bis[(η5-tri-tert-butylcyclopentadienyl)cobalt]:μ:[η4:η4-perylene]] | 656821-08-8

• 英文名称: [bis[(η5-tri-tert-butylcyclopentadienyl)cobalt]:μ:[η4:η4-perylene]]
• CAS: 656821-08-8
• 化学式: C₅₄H₇₀Co₂
• 分子量: 837.136
• InChiKey: WLWMYQOZXBBAOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(η5-1,2,4-tri-tert-butyl-C5H2)Co]2-μ-(η4:η4-toluene) 、 苝 以 乙醚 为溶剂， 以28%的产率得到[bis[(η5-tri-tert-butylcyclopentadienyl)cobalt]:μ:[η4:η4-perylene]]
  参考文献：
  名称：

  Coordination studies of polycondensed π-perimeters: mono-, di- and tri-nuclear cobalt sandwich complexes of tetracene, benzo[a]pyrene, triphenylene, benzo[b]triphenylene and perylene

  摘要：

  By means of arene ligand exchange of the triple deckers [{(eta(5)-R1-5C5)CO}(2)-(mu)-(eta(4):eta(4)-toluene)] (R1-5 = Me, R1-3 = tert-butyl) at room temperature a number of mono-, di-, and tri-nuclear sandwich complexes of the polycondensed aromatics polycyclic aromatic hydrocarbons (PAHs) tetracene, benzo[a]pyrene, perylene, triphenylene and benzo[a]triphenylene have been synthesized. For triphenylene and benzo[b]triphenylene however, a threefold coordination of [(eta(5)-C5Me5)Co] fragments in the periphery of these PAHs is found, tetracene allows for a twofold coordination of two [(eta(5)-C5Me5)Co fragments in the ring periphery leaving a central naphthalene unit of this PAH uncomplexed. Perylene serves as a twofold coordination site for [(eta(5)-1,2,4 tri-tert-butyl-C5H2)Co] fragments which are coordinated in each of the two naphthalene fragments of this pi-perimeter. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00109-9