trans-[Et(H)GaCl]2 | 362658-72-8

• 英文名称: trans-[Et(H)GaCl]2
• CAS: 362658-72-8
• 化学式: C₄H₁₂Cl₂Ga₂
• 分子量: 270.491
• InChiKey: XZTCSTYDXPNYPM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙烯 、 monochlorogallane 以 苯 为溶剂， 生成 trans-[Et(H)GaCl]2 、 trans-[Et(H)GaCl]2 、
  参考文献：
  名称：

  Some Chemical Properties of Monochlorogallane:  Decomposition to Gallium(I) Trichlorogallate(III), Ga⁺[GaCl₃H]^-, and Other Reactions

  摘要：

  Thermal decomposition of monochlorogallane, [H2GaCl](n), at ambient temperatures releases H-2 and results in the formation of gallium(I) species, including the new compound Ga[GaHCl3], which has been characterized crystallographic ally at 100 K (monoclinic P2(1)/n, a = 5.730(1), b = 6.787(1), c = 14.508(1) Angstrom, beta = 97.902(5)degrees) and by its Raman spectrum. The gallane suffers symmetrical cleavage of the Ga(mu -Cl)(2)Ga bridge in its reaction with NMe3 but unsymmetrical cleavage, giving [H2Ga(NH3)(2)]Cl-+(-), in its reaction with NH3. Ethene inserts into the Ga-H bonds to form first [Et(H)GaCl](2) and then [Et2GaCl](2).

  DOI：

  10.1021/ic010128x