[Et4N][Re2(CO)6(μ-OEt)2(4-hydroxypyridonate)(4-hydroxypyridine)] | 945735-05-7

• 英文名称: [Et4N][Re2(CO)6(μ-OEt)2(4-hydroxypyridonate)(4-hydroxypyridine)]
• CAS: 945735-05-7
• 化学式: C₈H₂₀N*C₂₀H₁₉N₂O₁₀Re₂
• 分子量: 950.046
• InChiKey: GURAFAXVZPHLHY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-羟基吡啶 、 乙醇 、 (NEt4)[Re2(μ-OH)3(CO)6] 以 乙醇 为溶剂， 以76%的产率得到[Et4N][Re2(CO)6(μ-OEt)2(4-hydroxypyridonate)(4-hydroxypyridine)]
  参考文献：
  名称：

  Synthesis and characterization of binuclear rhenium(I) complexes containing bifunctional ligands

  摘要：

  The ligand exchange reaction of the anionic binuclear rhenium complexes Re-2 (CO)(6) (OR)(3)(-) (R = H (1), or Me (2)) has been studied with the bifunctional ligands 2-aminophenol (3), 4-hydroxypyridine (4), 3-hydroxybenzoic acid (5), and 3-pyridylcarbinol (6). The reactivity the pendant pyridyl group of 6 was studied in reactions with the Lewis acids ZnCl2 (7), and AgPF6 (8). Crystal structure determinations for several of these derivatives have been carried out which reveal both discrete and polymeric complexes upon addition of the Lewis base. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.03.034