| 1219807-39-2

• CAS: 1219807-39-2
• 化学式: C₁₁₈H₁₄₄Cu₂N₄O₁₄
• 分子量: 1969.55
• InChiKey: LOMHNVWPZFMLTO-OMUXQDJWSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper diacetate 、 21,27,33,55,61,67,72,82-Octatert-butyl-10,44-dimethyl-3,17,37,51-tetraoxa-6,14,40,48-tetrazatridecacyclo[51.15.7.719,35.18,12.125,29.142,46.159,63.170,74.02,65.018,23.031,36.052,57.180,84]octaoctaconta-1,6,8,10,12(87),13,18,20,22,25,27,29(86),31,33,35,40,42(78),43,45,47,52,54,56,59(77),60,62,65,67,70,72,74(76),80(88),81,83-tetratriacontaene-76,77,78,86,87,88-hexol 以 甲醇 、 氯仿 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of a (1+1) cyclic Schiff base of a lower rim 1,3-diderivative of p-tert-butylcalix[4]arene and its complexes of VO2+, , Fe3+, Ni2+, Cu2+ and Zn2+

  摘要：

  A (1+1) macrocyclic calix[4]arene based Schiff base derivative has been synthesized and was subjected to complexation with different Ions or ionic species. viz, VO2+, UO22+, Fe-,(3+) Ni2+, CU2+ and Zn-.(2+) Both the conjugate and the complexes were characterized using various spectral techniques, viz, FTIR, H-1, C-13 NMR and FAB mass The complexes have been further characterized by UV-Vis, EPR and magnetic susceptibility, while the Iron complex was studied further by Mossbauer spectroscopy On the basis of all these studies, the VO2+ and UO22+ complexes were found to be mononuclear, whereas all the other complexes were found to be dinuclear. Based on the studies, the Iron complex was found have a distorted octahedral high spin Fe(III) center with an antiferromagnetically Coupled dinuclear core in the complex. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.12.020