| 1416345-57-7

• CAS: 1416345-57-7
• 化学式: C₂₇H₁₃BF₁₂O₂
• 分子量: 608.191
• InChiKey: IFCDQFKBZUWPRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氘代苯 为溶剂， 反应 0.17h， 生成 Ethylidyneazaniumyl-tris(2,3,5,6-tetrafluorophenyl)boranuide
  参考文献：
  名称：

  Comparative Lewis Acidity in Fluoroarylboranes: B(o-HC₆F₄)₃, B(p-HC₆F₄)₃, and B(C₆F₅)₃

  摘要：

  The Lewis acidic fluoroarylborane B(o-HC6F4)(3) (2) was prepared and its Lewis acid strength assessed in comparison to the known, related boranes B(C6F5)(3) (1) and B(p-HC6F4)(3) (3). Experimental methods based on spectroscopic probes and equilibrium measurements were used to show that B(C6F5)(3) is the strongest Lewis acid of the three; while the Lewis acidities of 2 and 3 are comparable, the p-H-substituted isomer is slightly stronger in the tests employed. This contrasts with predictions made on the basis of computed bond formation energies, as recently reported by Durfey and Gilbert.

  DOI：

  10.1021/om3011195
• 作为产物：
  描述：

  Ethylidyneazaniumyl-tris(2,3,5,6-tetrafluorophenyl)boranuide 以 二氯甲烷-D2 、 氘代苯 为溶剂， 生成
  参考文献：
  名称：

  Comparative Lewis Acidity in Fluoroarylboranes: B(o-HC₆F₄)₃, B(p-HC₆F₄)₃, and B(C₆F₅)₃

  摘要：

  The Lewis acidic fluoroarylborane B(o-HC6F4)(3) (2) was prepared and its Lewis acid strength assessed in comparison to the known, related boranes B(C6F5)(3) (1) and B(p-HC6F4)(3) (3). Experimental methods based on spectroscopic probes and equilibrium measurements were used to show that B(C6F5)(3) is the strongest Lewis acid of the three; while the Lewis acidities of 2 and 3 are comparable, the p-H-substituted isomer is slightly stronger in the tests employed. This contrasts with predictions made on the basis of computed bond formation energies, as recently reported by Durfey and Gilbert.

  DOI：

  10.1021/om3011195