tetrakis(triphenoxy-l5-phosphaneyl)rhodium(V) hexafluorophosphate(V) | 620168-53-8

• 英文名称: tetrakis(triphenoxy-l5-phosphaneyl)rhodium(V) hexafluorophosphate(V)
• CAS: 620168-53-8
• 化学式: C₇₂H₆₀O₁₂P₄Rh*F₆P
• 分子量: 1489.03
• InChiKey: DOIUMVSLPXLCSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 hydridotetrakis(triphenyl phosphite)rhodium(I) 以 二氯甲烷 为溶剂， 生成 tetrakis(triphenoxy-l5-phosphaneyl)rhodium(V) hexafluorophosphate(V)
  参考文献：
  名称：

  Cationic rhodium(I) complexes formed in the reactions of HRh(CO)L3 (L=PPh3, P(OPh)3) complexes with silver(I) salts

  摘要：

  The reactions of HRh(CO)L-3 (L=PPh3, P(OPh)(3)) complexes with AgY (Y=BF4-, CF3SO3-, PF6-) lead to [Rh(CO)(PPh3)(2)(H2O)]Y and [Rh (CO)(P(OPh)(3))(3)]Y compounds. The solvolysis of [Rh(CO)(PPh3)(2)(H2O)]PF6 in ethanol produced a crystalline trans-[Rh(CO)(PPh3)(2)(OPOF2)] complex containing distorted square-planar rhodium center. The different arrangement of OPOF2- ligands found in two crystallographically independent molecules is connected with the presence of intra- and intermolecular C-H...O hydrogen bonds involving both oxygen atoms of each OPOF2- anion. The reaction of [Rh(CO)(P(OPh)(3))(3)]Y (Y=BF4-, PF6-) in solution with CO leads to [Rh(CO)(2)(P(OPh)(3))(3)]Y and with P(OPh)(3) to [Rh(P(OPh)(3))(4)]Y complexes. The [Rh(P(OPh)(3))(4)]PF6 complex was also obtained as a final reaction product of HRh(P(OPh)(3))(4) with AgPF6. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01551-7