| 491832-96-3

• CAS: 491832-96-3
• 化学式: C₁₉H₄AlF₁₅O
• 分子量: 560.198
• InChiKey: XDUJNTHOACUGMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氘代甲苯 为溶剂， 生成
  参考文献：
  名称：

  First Isolation and Structural Characterization of Triarylaluminum−Water and −Methanol Complexes

  摘要：

  The structurally characterized (C6F5)(3)Al.OH2 (1) and (C6F5)(3)Al-OHCH3 (2) exhibit medium-strong intermolecular and weak intramolecular O-H...FC hydrogen bonds in the solid state. Both complexes have substantial stability in toluene solutions at room temperature, while the spectroscopic data of 1 show strong activation of the weak Bronsted acid H2O by Al(C6F5)(3).

  DOI：

  10.1021/om020834l
• 作为产物：
  描述：

  甲醇 、 tris(pentafluorophenyl)aluminum*(toluene)0.5 以 正己烷 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  First Isolation and Structural Characterization of Triarylaluminum−Water and −Methanol Complexes

  摘要：

  The structurally characterized (C6F5)(3)Al.OH2 (1) and (C6F5)(3)Al-OHCH3 (2) exhibit medium-strong intermolecular and weak intramolecular O-H...FC hydrogen bonds in the solid state. Both complexes have substantial stability in toluene solutions at room temperature, while the spectroscopic data of 1 show strong activation of the weak Bronsted acid H2O by Al(C6F5)(3).

  DOI：

  10.1021/om020834l