rubidium tetrafluoroantimonate(III) | 36795-67-2

• 英文名称: rubidium tetrafluoroantimonate(III)
• CAS: 36795-67-2
• 化学式: F₄Sb*Rb
• 分子量: 283.211
• InChiKey: RLQQQYBFUHTOJJ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  rubidium fluoride 、 三氟化锑 以 水 为溶剂， 生成 rubidium tetrafluoroantimonate(III)
  参考文献：
  名称：

  Kavun; Udovenko; Uvarov, Russian Journal of Inorganic Chemistry, 2003, vol. 48, # 6, p. 874 - 879

  摘要：

  DOI：

文献信息

• Ion Mobility, Phase Transitions, and Ion Conductivity in Alkali Metal Tetrafluoroantimonates(III) MSbF₄(M = Na, K, Rb, Cs)
  作者：V. Ya. Kavun、N. F. Uvarov、V. I. Sergienko、L. A. Zemnukhova

  DOI：10.1023/b:ruco.0000034792.37391.5c

  日期：2004.7

  The internal mobility of fluoride ions and electrophysical characteristics of alkali metal tetrafluoroantimonates(III) (M = Na, K, Rb, and Cs) are studied by F-19 NMR and impedance spectroscopies. The types of ion motions in the anionic sublattice of these compounds are determined in the 180-510 K temperature range. The superionic conductivity of the MSbF4 compounds is established above 480 K (sigma similar to 2.9 x 10(-2) to 1.3 x 10(-4) S/cm).
• The Crystal Structures of Rubidium and 4-Amino-1,2,4-Triazolium Tetrafluoroantimonates(III)
  作者：A. A. Udovenko、L. A. Zemnukhova、E. V. Kovaleva、Yu. E. Gorbunova、Yu. N. Mikhailov

  DOI：10.1023/b:ruco.0000037433.84613.af

  日期：2004.8

  The crystal structures of complex antimony(III) fluorides RbSbF4 (I) and (C2N4H5)SbF4 (II) were determined. The crystals of I and II are monoclinic; for I: a = 4.628(1) Angstrom, b = 6.167(1) Angstrom, c = 7.922(1) Angstrom, beta = 100.582(3)degrees, V = 222.24(7) Angstrom(3), Z = 2, rho(calcd.) = 4.23 g/cm(3), rho(exp.) = 4.25 g/cm(3), F(000) = 248, space group P2(1)/m, R = 0.0395; for II: a = 4.678(1) Angstrom, b = 7.339(4) Angstrom, c = 10.185(1) Angstrom, beta = 90.88(2)degrees, V = 349.6(2) Angstrom(3), Z = 2, rho(calcd.) = 2.69 g/cm(3), rho(exp.) = 2.70 g/cm(3), F(000) = 264, space group P2(1). The structure of I is formed by Rb+ cations and [SbF4](n)(n-) anionic chains composed of SbF5E octahedra with two bridging fluorine atoms. The structure of II is formed by (C2N4H5)(+) cations and isolated [SbF4](-) anions in which the antimony polyhedra are SbF4E trigonal bipyramids. The relationship between the crystal structures and electrophysical and biological properties of single-charged cation tetrafluoroantimonates(III) was studied.