| 197980-27-1

• CAS: 197980-27-1
• 化学式: C₃₃H₂₆BF₁₅Si₂Zr
• 分子量: 865.751
• InChiKey: SCUAUUFOIRJGCH-FHJHGPAASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氘代甲苯 为溶剂， 生成
  参考文献：
  名称：

  Construction of a Borole Ligand from Coordinated Diene and B(C₆F₅)₃ via Successive C−H Activation Steps:  A Case of Catalyst Self-Activation

  摘要：

  DOI：

  10.1021/ja981069y
• 作为产物：
  描述：

  以 not given 为溶剂， 生成
  参考文献：
  名称：

  Novel Zwitterionic Diallylzirconium Complexes: Synthesis, Structure, Polymerization Activity, and Deactivation Pathways

  摘要：

  DOI：

  10.1002/anie.199723581

文献信息

• Jimenez Pindado, Gerardo; Thornton-Pett, Mark; Bochmann, Manfred, Journal of the Chemical Society, Dalton Transactions
  作者：Jimenez Pindado, Gerardo、Thornton-Pett, Mark、Bochmann, Manfred

  DOI：——

  日期：——
• The versatile chemistry of metallocene polymerisation catalysts: new developments in half-sandwich complexes and catalyst heterogenisation
  作者：Manfred Bochmann、Gerardo Jiménez Pindado、Simon J. Lancaster

  DOI：10.1016/s1381-1169(99)00064-3

  日期：1999.10

  Metallocene complexes of Group 4 metals are playing an increasingly important role in olefin polymerisation catalysis. This contribution surveys several aspects of the chemistry of metallocene catalysts that are being pursued in our laboratory at present, namely the application of half-sandwich complexes as catalysts for high-molecular weight elastomeric polypropene, unusual C-H activation reactions of zirconium half-sandwich complexes, the development of 14-electron borole complexes as neutral analogues of cationic [Cp2ZrR](+) catalysts, and the heterogenisation of MAO-free zirconocene catalysts on borate-functionalised silica. (C) 1999 Elsevier Science B.V. All rights reserved.