[Zn(1,4,8,11,15,18,22,25-octachloro-2,3,9,10,16,17,23,24-octakis(decylsulfanyl)phthalocyanine)] | 1062222-14-3

• 英文名称: [Zn(1,4,8,11,15,18,22,25-octachloro-2,3,9,10,16,17,23,24-octakis(decylsulfanyl)phthalocyanine)]
• CAS: 1062222-14-3
• 化学式: C₁₁₂H₁₆₈Cl₈N₈S₈Zn
• 分子量: 2232.16
• InChiKey: ZBVIZVDWNZRZBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3,6-dichloro-4,5-bis(n-decylsulfanyl)phthalonitrile 、 zinc diacetate 在 ammonium molybdate 作用下， 以 melt 为溶剂， 生成 [Zn(1,4,8,11,15,18,22,25-octachloro-2,3,9,10,16,17,23,24-octakis(decylsulfanyl)phthalocyanine)]
  参考文献：
  名称：

  Phthalocyanines and related compounds: XLIII. Synthesis of poly[phenyl(alkyl)sulfanyl]-substituted phthalonitriles and some phthalocyanines based thereon

  摘要：

  Nucleophilic substitution of chlorine atoms in tetrachlorophthalonitrile by benzene- and alkanethiols in the presence of a base was studied at different reactant ratios. The substitution is characterized by complete regioselectivity: the chlorine atom in position 4 of tetrachlorophthalonitrile is replaced first; next follows replacement of the 5-chlorine atom. The reactions of tetrachlorophthalonitrile with nucleophiles at ratios of 1:2 and 1:4 lead to the formation of the corresponding 3,6-dichloro-4,5-bis[phenyl(alkyl)sulfanyl]- and tetrakis[phenyl(alkyl)sulfanyl]phthalonitriles. The latter were converted into metal complexes of [phenyl-(alkyl)sulfanyl]-substituted phthalocyanines which absorb in the red and near-IR regions of the electronic spectra.

  DOI：

  10.1134/s107036320706028x