| 136676-60-3

• CAS: 136676-60-3
• 化学式: Li₃MoS₂
• 分子量: 180.895
• InChiKey: RXHYFICHDUIIQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.72
• 重原子数：
  6.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  molybdenum (IV) sulfide 、 lithium 以 氨 为溶剂， 生成
  参考文献：
  名称：

  Decomposition of tetrahydrofuran on molybdenum disulfide and lithium molybdenum sulfide (LixMoS2)

  摘要：

  Chemisorption and thermal evolution of tetrahydrofuran (THF) on various MoS2 surfaces were studied by C-13 CP/MAS NMR spectroscopy. In all cases the adsorption is nondissociative at room temperature. On pure MoS2, decomposition of the adsorbed layer begins at 150-degrees-C, the initial reaction product being aldehyde. ON LiMoS2, reaction begins at a higher temperature, while on Li3MoS2 the initial product is chemisorbed butoxide. At high temperatures, the carbon from THF is converted entirely to small aliphatic hydrocarbons, CO2, and adsorbed aromatic residues.

  DOI：

  10.1021/j100177a055