[((η(5)-C5H5)Fe(η(5)-C5H3(N-(2-N',N'-(dimethylaminoethyl)-N-methyl-aminoethyl)))(1-))2SnCl2] | 859731-73-0

• 英文名称: [((η(5)-C5H5)Fe(η(5)-C5H3(N-(2-N',N'-(dimethylaminoethyl)-N-methyl-aminoethyl)))(1-))2SnCl2]
• 英文别名: [(η(5)-C5H5)Fe(η(5)-C5H3(N-(2-N',N'-(Dimethylaminoethyl)-N-methyl-aminoethyl)))(1-))2SnCl2]
• CAS: 859731-73-0
• 化学式: C₃₄H₅₀Cl₂Fe₂N₄Sn
• 分子量: 816.108
• InChiKey: UQXGSISIOCBLIM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 [((η(5)-C5H5)Fe(η(5)-C5H3(N-(2-N',N'-(dimethylaminoethyl)-N-methyl-aminoethyl)))(1-))2SnCl2] 以 甲醇 、 二氯甲烷 为溶剂， 生成 [(η(5)-C5H5)Fe(η(5)-C5H3(N-(2-N',N'-(Dimethylaminoethyl)-N-methyl-aminoethyl)))(1-))2SnCl2]*0.5MeOH
  参考文献：
  名称：

  Synthese und Kristallstruktur des heterobimetallischen Diorganozinndichlorids (FcN, N)2SnCl2 (FcN, N?: (?5-C5H5)Fe{(?5-C5H3[CH(CH3)N(CH3)CH2CH2NMe2]-2}?)

  摘要：

  AbstractSynthesis and Crystal Structure of the Heterobimetallic Diorganotindichloride (FcN, N)2SnCl2 (FcN, N—: (η5‐C5H5)Fe{η5‐C5H3[CH(CH3)N(CH3)CH2CH2NMe2]‐2}—)The heterobimetallic title compound [(FcN, N)2SnCl2] (1) was obtained by the reaction of [LiFcN, N] with SnCl4 in the molar ratio 1:1 in diethylether as a solvent. The two FcN, N— ligands in 1 are bound to Sn through a C‐Sn σ‐bond; the amino N atoms of the side‐chain in FcN, N— remain uncoordinated. The crystals contain monomeric molecules with a pseudo‐tetrahedral coordination at the Sn atom: Space group P21/c; Z = 4, lattice dimensions at —90 °C: a = 9.6425(2), b = 21.7974(6), c = 18.4365(4) Å, β = 100.809(2)°, R1obs· = 0.051, wR2obs· = 0.136.

  DOI：

  10.1002/zaac.200400412
• 作为产物：
  描述：

  Li[(η(5)-C5H5)Fe(η(5)-C5H3(N-(2-N',N'-(Dimethylaminoethyl)-N-methyl-aminoethyl)))(1-)] 、 四氯化锡 以 乙醚 为溶剂， 以35.46%的产率得到[((η(5)-C5H5)Fe(η(5)-C5H3(N-(2-N',N'-(dimethylaminoethyl)-N-methyl-aminoethyl)))(1-))2SnCl2]
  参考文献：
  名称：

  Synthese und Kristallstruktur des heterobimetallischen Diorganozinndichlorids (FcN, N)2SnCl2 (FcN, N?: (?5-C5H5)Fe{(?5-C5H3[CH(CH3)N(CH3)CH2CH2NMe2]-2}?)

  摘要：

  AbstractSynthesis and Crystal Structure of the Heterobimetallic Diorganotindichloride (FcN, N)2SnCl2 (FcN, N—: (η5‐C5H5)Fe{η5‐C5H3[CH(CH3)N(CH3)CH2CH2NMe2]‐2}—)The heterobimetallic title compound [(FcN, N)2SnCl2] (1) was obtained by the reaction of [LiFcN, N] with SnCl4 in the molar ratio 1:1 in diethylether as a solvent. The two FcN, N— ligands in 1 are bound to Sn through a C‐Sn σ‐bond; the amino N atoms of the side‐chain in FcN, N— remain uncoordinated. The crystals contain monomeric molecules with a pseudo‐tetrahedral coordination at the Sn atom: Space group P21/c; Z = 4, lattice dimensions at —90 °C: a = 9.6425(2), b = 21.7974(6), c = 18.4365(4) Å, β = 100.809(2)°, R1obs· = 0.051, wR2obs· = 0.136.

  DOI：

  10.1002/zaac.200400412