| 1174403-29-2

• CAS: 1174403-29-2
• 化学式: C₃₂H₂₀Br₂N₂O₆Re₂
• 分子量: 1060.74
• InChiKey: HVVOPYHJQXYEMF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯甲酮吖嗪 、 bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer 以 二氯甲烷 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Mono- and di-nuclear 2,3-diazabutadiene and 2-azabutadiene complexes of Rhenium(I): Syntheses, luminescence spectra and X-ray structures

  摘要：

  Treatment of [Re(CO)(3)(THF)(mu-Br)](2) with 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene [Cl2C=C(H)-N= CPh2] (1a) yields the di-nuclear benzophenone azine-bridged compound [(OC)(3)Re(mu-Ph2C=N-N=CPh2)-(mu-Br)(2)Re(CO)(3)] (2a), albeit in low yield. Alternatively, compounds [(OC)(3)Re(mu-Ph2C=N-N=CPh2)(mu-X)(2)-Re(CO)(3)] (2a,b) (X=Br, Cl) are obtained in high yields by direct reaction of [Re(CO)(3)(THF)(mu-Br)](2) or [Re(CO)(5)Cl] with benzophenone azine. Nucleophilic attack of NaSPh on 1a affords the 2-azabutadiene derivative [(PhS)(Cl)C=C(H)-N=CPh2] (1b). which upon reaction with [Re(CO)(3)(THF)(mu-Br)](2) forms the S,N-chelate complex fac-[(OC)(3)ReBr((PhS)(Cl)C=C(H)-N=CPh2)] (3). The crystal structures of 1b, 2a and 3 have been determined and the luminescence properties of 2 and 3 have been investigated. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.05.022