dichloro(4-acetylpyridine thiosemicarbazone)copper(II) | 111764-06-8

• 英文名称: dichloro(4-acetylpyridine thiosemicarbazone)copper(II)
• CAS: 111764-06-8
• 化学式: C₈H₁₀Cl₂CuN₄S
• 分子量: 328.712
• InChiKey: FWIWTZLUQZRYAC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper dichloride 、 (1-吡啶-4-基乙亚基氨基)硫脲 以 甲醇 为溶剂， 生成 dichloro(4-acetylpyridine thiosemicarbazone)copper(II)
  参考文献：
  名称：

  Synthesis, catalytic oxidation and antimicrobial activity of copper(II) Schiff base complex

  摘要：

  A new polymer supported Cu(II) Schiff base complex was synthesized. The solid complex was characterized by Fourier transform infrared spectroscopy (FT-IR), UV-vis diffuse reflectance spectroscopy (DRS), thermogravimetric analysis (TGA) and scanning electron microscope (SEM). Its homogeneous analogue was also prepared. The catalytic performances of the copper complex in oxidation reactions were evaluated for both homogeneous and heterogeneous systems. The copper(II) complex was found to be efficient catalyst for the oxidation of alkenes, alkanes and aromatic alcohols in the presence of hydrogen peroxide as oxidant at room temperature. The catalytic investigation revealed that the solid complex performs better than the homogeneous one as an oxidation catalyst. The solids containing the immobilized complex can be recovered from the reaction medium and reused almost five times, maintaining good catalytic activity. Furthermore, the in vitro toxicity of the ligand and complex was tested against the growth of bacterial species, viz., Staphylococcus aureus and Escherichia coli. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2011.01.006