[Tp(Me2)Ir(C6H4(COOCH3)6)] | 501330-63-8

• 英文名称: [Tp(Me2)Ir(C6H4(COOCH3)6)]
• 英文别名: [(hydrotris(3,5-dimethylpyrazolyl)borate)Ir(C6H4(COOCH3)6)]
• CAS: 501330-63-8
• 化学式: C₂₉H₃₈BIrN₆O₈
• 分子量: 801.687
• InChiKey: ZZSKKGMXOKDWNU-UTAAMMLDSA-N

反应信息

• 作为产物：
  描述：

  [Tp^Me2Ir(C₂H₄)₂] 、 丁炔二酸二甲酯 以 二氯甲烷 为溶剂， 生成 [Tp(Me2)Ir(C6H4(COOCH3)6)]
  参考文献：
  名称：

  Coupling of Internal Alkynes in Tp^Me2Ir Derivatives:  Selective Oxidation of a Noncoordinated Double Bond of the Resulting Iridacycloheptatrienes

  摘要：

  The reaction of different Tp(Me2)Ir derivatives and dimethylacetylene dicarboxylate (DMAD) allows the preparation of three different metallacycloheptatriene complexes and an unusual allyl-terminated metallacycle. The C atoms of distant C=C bonds in the metallacycles, including aromatic ones, can be converted selectively to the corresponding keto functionality under mild conditions.

  DOI：

  10.1021/ja0290375