| 1403588-16-8

• CAS: 1403588-16-8
• 化学式: C₃₆H₁₈N₈O₆Re₂S₆
• 分子量: 1223.4
• InChiKey: WTLHMIZGLJMILN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis{1,2-(benzothiazol-2-ylidene)}thiourea 、 五羰基氯铼(I) 以 甲苯 为溶剂， 反应 3.0h， 以65%的产率得到
  参考文献：
  名称：

  Dimers of the fac-[Re(CO)3]+ core with benzothiazole derivatives of thiourea

  摘要：

  The products of the reactions of [Re(CO)(5)Cl] with 1-(benzothiazol-2-ylidene)-3-methylthiourea (Hmbt) and bis {1,2-(benzothiazol-2-ylidene)}thiourea (Hdbt) were studied. The X-ray crystal structure of (mu-mbt)(2)[Re(CO)(3)](2) shows that bridging between the two metal centres occurs via the two thiolic sulfur atoms of the two mbt ligands. One mbt ligand is also coordinated via a benzothiazole nitrogen atom to a rhenium(I) atom, with the second mbt ligand attached to the metal via a thiourea imino nitrogen. In the complex (mu-dbt)(2)[Re(CO)(3)](2). each dbt ligand bridges two metal centres in a '2 + 1' manner, with each rhenium atom in a N2SC3 donor atom set. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.07.022