| 89014-85-7

• CAS: 89014-85-7；444614-56-6；729610-58-6；107966-62-1
• 化学式: C₆H₈CuNa₂O₁₀
• 分子量: 349.649
• InChiKey: ISJPUVYJBNXMSG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium hydroxide 、 水 、 苯酐 、 copper dichloride 、 sodium malonate 以 水 为溶剂， 生成 、
  参考文献：
  名称：

  Two novel heterometallacrowns: syntheses and crystal structures of two copper(II) complexes with malonate and o-pthalate

  摘要：

  Two copper(II) sodium(l) coordination compounds of formula [C16H12CuNa2O10] (1) and [C6H8CuNa2O10] (2) were prepared and their structures were characterized by single-crystal X-ray diffraction, IR spectra and thermal analyses. In complex 1, the sodium atom is six coordinated with four carboxylate oxygens from two o-pthalate ligands, another one oxygen atom from one o-pthalate and one water molecule building a distorted octahedron. All the four oxygen atoms in one o-pthalate participate in coordination, two of which bridge one sodium and one copper atoms, with another one bridging two sodium atoms and the fourth coordinating one sodium atom. As for complex 2, the sodium atom is also six-coordinated with tetrakis-monodentate malonate oxygen atoms and two water molecules building a distorted octahedron. For every malonate, three oxygens coordinate out of the total four. Every carboxylate offers an oxygen atom bridging one sodium and one copper atom with the remaining one bridging two sodium atoms. In both cases, each copper atom is in a square planar environment formed by four carboxylate-oxygens from four o-pthalates and two malonates respectively. The IR spectra also testify the structure detection. Thermal analyses of the two complexes were also carried out. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.11.059