[Re2(OCH2CH2OH)2(CO)6(4,4'-bipyridine)]2 | 213681-19-7

• 英文名称: [Re2(OCH2CH2OH)2(CO)6(4,4'-bipyridine)]2
• CAS: 213681-19-7
• 化学式: C₄₀H₃₆N₄O₂₀Re₄
• 分子量: 1637.57
• InChiKey: GWQIIYZETNRQIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 [Re(OTf)(CO)₅] 、 乙二醇 以 乙二醇 为溶剂， 以99%的产率得到[Re2(OCH2CH2OH)2(CO)6(4,4'-bipyridine)]2
  参考文献：
  名称：

  Self-Assembly of Ligand-Bridged Molecular Rectangles Containing fac-Re(CO)₃ Corners

  摘要：

  A series of molecular rectangles have been synthesized by self-assembly using Re(CO)(5)OTf, 4,4'-bipyridine and an alcohol or water. The rectangles have been characterized by elemental analysis as well as IR,H-1 NMR and UV-visible spectroscopies, and in one case cyclic voltammetry and an X-ray structure determination. These complexes are representatives of a new structural class of molecular parallelograms containing the unusual combination of carbon monoxide and alkoxide ligands around a Re(I) center.

  DOI：

  10.1021/ic9805168