[Zn(2-(o-tolylazo)pyridine)Cl2*CH3OH] | 366007-11-6

• 英文名称: [Zn(2-(o-tolylazo)pyridine)Cl2*CH3OH]
• CAS: 366007-11-6
• 化学式: C₁₃H₁₅Cl₂N₃OZn
• 分子量: 365.578
• InChiKey: UVDUNUBOIAUJLM-YRWWQZRJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 zinc(II) chloride dihydrate 、 2-[(2-methylphenyl)azo]pyridine 以 甲醇 为溶剂， 生成 [Zn(2-(o-tolylazo)pyridine)Cl2*CH3OH]
  参考文献：
  名称：

  Synthesis, spectral and electrochemical studies of 2-(arylazo)heterocycle complexes of zinc(II). Single-crystal X-ray structure of [Zn(papm)Cl2·CH3OH] (papm=2-(phenylazo)pyrimidine)

  摘要：

  2-(Arylazo)pyridines (aap) (R-C6H4-N=N-C5H4N, 1) and 2-(arylazo)pyrimidines (aapm) (R-C6H4-N=N-C4H3N2, 2); R = H (a), o-Me (b), m-Me (c), p-Me (d), p-Cl (e) are used to synthesise title compounds. The complexes are characterised by elemental analyses, IR, UV-Vis and H-1 NMR spectral data. Single-crystal X-ray structure of dichloro-{2-(phenylazo)pyrimidinelzine}-zinc(II)(.)methanol suggests that the complex is a distorted trigonal bipyramidal symmetric around Zn(II), and Cl(1), Cl(2), N(4) (N (azo)) make the trigonal plane. Zn(II) moves downwards by 0.12 Angstrom from the centre of gravity of the plane. Two axial positions are occupied by N(1) (N(pyrimidine)) and methanol-O. Molecular packing shows one-dimensional infinite chain via hydrogen bonding. The EHMO calculation has been carried out to explain the electronic behaviour of the complexes and the results are compared with that of copper(I) complex. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00824-5