| 68825-54-7

• CAS: 68825-54-7
• 化学式: C₃₂H₂₃O₂Sn
• 分子量: 558.243
• InChiKey: TXJRTCTYHSJSOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六苯基二锡 、 菲醌 以 二氯甲烷 为溶剂， 生成 、 、
  参考文献：
  名称：

  Studies of organotin(IV)-orthoquinone systems1Dedicated to Professor Ken Wade on the occasion of his 65th Birthday in recognition of his outstanding contributions to Main Group Chemistry.1

  摘要：

  The primary process in the reaction of hexaphenylditin with various substituted orthoquinones (Q) is shown to involve attack by the quinone at a phenyl ligand. The intermediate thus formed decomposes to yield Ph3Sn(SQ(.)), where S(Q(.-)) is the corresponding semiquinonate. Rearrangement of these species in solution gives rise to biradicals, while intramolecular electron transfer may lead to the formation and precipitation of Ph2Sn(CAT), where CAT(2-) is the corresponding substituted catecholate. The identification of these processes depends in part on electron paramagnetic resonance spectroscopy. The reaction of Ph3SnCl or Ph2SnCl2 with Na(TBSQ(.)) (TBSQ(.-) = 3,5-di-tert-butyl-orthobenzosemiquinonate) results in the formation of Ph2Sn(TBSQ(.)), which can undergo redistribution and intramolecular electron transfer, so that the solution chemistry of these latter systems is similar to that of the products of the Sn2Ph6 + Q reaction. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00538-x

文献信息

• Molecular structure of diphenylbis(9,10-phenanthrenesemiquinonate)tin(iv), an organometallic diradical complex
  作者：Andrei S. Batsanov、Judith A. K. Howard、Martyn A. Brown、Bruce R. McGarvey、Dennis G. Tuck

  DOI：10.1039/a608391i

  日期：——

  The title compound, formed in the reaction between hexaphenylditin and 9,10-phenanthrenequinone, is shown to be an organotin(IV) diradical; its X-ray structure and EPR spectra are reported.

  六苯基二硝基锡与 9,10-菲醌反应生成的标题化合物被证明是一种有机锡（IV）二元化合物；报告了其 X 射线结构和 EPR 光谱。