Synthesis and studies of chemical properties of arylthallium(III)bis(tetrafluoroborates)
摘要:
Synthesis of arylthallium(III)bis(tetrafluoroborates) was carried out and their pyrolysis was studied. Synthetic procedure for preparation of fluoroaromatic compounds is developed.
Thallium(III) oxide as an oxidative reagent in organic chemistry
作者:I. F. Gun’kin
DOI:10.1134/s1070363210030138
日期:2010.3
Oxidative properties of thallium(III) oxide in various organic reactions were studied. Oxidative bromination of organic compounds in Tl2O3-KBr-trifluoroacetic acid system was carried out. New synthetic method for preparation of diphenylthallium salts from phenylhydrazine and thallium(III) oxide was developed.
研究了氧化organic(III)在各种有机反应中的氧化性能。在Tl 2 O 3 -KBr-三氟乙酸体系中进行有机化合物的氧化溴化。提出了由苯肼和氧化preparation制备二苯基th盐的新方法。
Gun'kin; Pankst'yanov; Popova, Russian Journal of General Chemistry, 2000, vol. 70, # 1, p. 37 - 39