η6-meta-xylene molybdenum(0) tricarbonyl | 12288-65-2

• 英文名称: η6-meta-xylene molybdenum(0) tricarbonyl
• CAS: 12288-65-2
• 化学式: C₁₁H₁₀MoO₃
• 分子量: 286.139
• InChiKey: ZQJVSIFFDJYPLD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  间二甲苯 、 molybdenum hexacarbonyl 以 xylene 为溶剂， 以47%的产率得到η6-meta-xylene molybdenum(0) tricarbonyl
  参考文献：
  名称：

  Intra- vs. intermolecular configurations in the three-legged, piano-stool compounds (o, m and p-xylene)Mo(CO)3

  摘要：

  The three (eta(6)-xylene)Mo(CO)(3) complexes have been prepared and crystallographically characterized to determine the rotational relationship of the arene ring to the undercarriage, as has been suggested by theoretical studies. In fact, no such relationship can be seen, especially when combined with eight examples of structures with Z'> 1, where both staggered and eclipsed forms are found. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.08.014