[Cu(6,13-bis(dodecylaminomethylidene)-1,4,8,11-tetrazacyclotetradeca-4,7,11,14-tetraene)][hexabromorhenium(IV)] | 473681-50-4

• 英文名称: [Cu(6,13-bis(dodecylaminomethylidene)-1,4,8,11-tetrazacyclotetradeca-4,7,11,14-tetraene)][hexabromorhenium(IV)]
• CAS: 473681-50-4
• 化学式: Br₆Re*C₃₆H₆₆CuN₆
• 分子量: 1312.14
• InChiKey: AXAQSXQFRFSTHH-FTGAHWAVSA-H

反应信息

• 作为产物：
  描述：

  (NBu₄)₂[ReBr₆] 、 [Cu(6,13-bis(dodecylaminomethylidene)-1,4,8,11-tetrazacyclotetradeca-4,7,11,14-tetraene)][PF6]2 以 乙腈 为溶剂， 以90%的产率得到[Cu(6,13-bis(dodecylaminomethylidene)-1,4,8,11-tetrazacyclotetradeca-4,7,11,14-tetraene)][hexabromorhenium(IV)]
  参考文献：
  名称：

  Ferrimagnetic chain compounds [CuL]ReCl6·H2O and [CuL]ReBr6 (where L=6,13-bis(dodecylaminomethylidene)-1,4,8,11-tetrazacyclotetradeca-4,7,11,14-tetraene)

  摘要：

  A new kind of binuclear compounds of rhenium(IV) with highly unsaturated cyclidene copper(IT) complex cation [CuL](2+) (L = 6,13-bis(dodecylaminomethylidene)-1,4,8,11-tetrazacyclotetradeca-4,7,11,14-tetraene) have been synthesized and magnetically characterized. Their magnetic behaviors are typical for a ferrimagnetic Cu(II)Re(IV) bimetallic chain with intrachain antiferromagnetic coupling. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(02)00135-7