[Re(CO)3(1,1'-bis(diphenylphosphino)ferrocene)(MeCN)] triflate | 1316251-56-5

• 英文名称: [Re(CO)3(1,1'-bis(diphenylphosphino)ferrocene)(MeCN)] triflate
• CAS: 1316251-56-5
• 化学式: CF₃O₃S*C₃₉H₃₁FeNO₃P₂Re
• 分子量: 1014.75
• InChiKey: ZDUVRMVRNRMKLL-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  fac-[Re(CO)3(triflate)(1,1'-bis(diphenylphosphino)ferrocene)] 、 乙腈 以 乙腈 为溶剂， 以93%的产率得到[Re(CO)3(1,1'-bis(diphenylphosphino)ferrocene)(MeCN)] triflate
  参考文献：
  名称：

  Non-innocent ligand reservoirs for reducing or oxidizing equivalents in carbonylrhenium(I) complexes: 1,1′-Bis(diphenylphosphino)ferrocene (dppf) and bis-triazinyl-pyridine (BTP)

  摘要：

  Organometallic complexes of Re(I) with ligands having opposite redox properties have been synthesized and structurally characterized. X-ray crystal structures of the complexes show typical fac-Re-I(CO)(3) coordination to the redox active ligands. Complete electrochemical and spectroelectrochemical studies on the ligands and the metal complexes were performed. The IR-spectroelectrochemical responses were monitored using the fac-Re(CO)(3) unit as a probe. The 15-20 cm(-1) hypsochromic or bathochromic shift of the nu(CO) bands upon reduction or oxidation is attributed to ligand-centered processes. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.005