chloro-(5,10,15,20-tetraphenyl-21-oxaporphyrinato)copper(II) | 209914-80-7

• 英文名称: chloro-(5,10,15,20-tetraphenyl-21-oxaporphyrinato)copper(II)
• CAS: 209914-80-7
• 化学式: C₄₄H₂₈ClCuN₃O
• 分子量: 713.725
• InChiKey: SPJLAYSYZPQDCZ-GIAQKWRESA-M

反应信息

• 作为反应物：
  描述：

  chloro-(5,10,15,20-tetraphenyl-21-oxaporphyrinato)copper(II) 、 tris-(4-bromophenyl)aminium hexachloroantimonate 以 二氯甲烷 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Spectral, magnetic and electrochemical properties of metal oxa- and oxathia-porphyrins

  摘要：

  Metal derivatives (CuII, NiII) of monooxa-, dioxa- and oxathia-tetraphenylporphyrins and their one-electron oxidised and reduced species have been studied. Electronic spectra of the monooxa and oxathia derivatives exhibit split Soret bands and a complicated pattern of Q-bands revealing their lower symmetry. The spectra of one-electron reduced species show only marginal shifts while the one-electron oxidised product of copper monooxaporphyrins show broad, red-shifted bands. Cyclic voltammetric studies indicated one-electron metal-centered reduction at fairly low potentials forming copper(I) and nickel(I) porphyrins. The ring-oxidised product exhibits weak antiferromagnetic interaction between the unpaired electrons of copper and the porphyrin ring. The ESR spectra of the copper dioxa- and oxathia-porphyrins exhibit rhombic symmetry with unusually small metal hyperfine couplings. A comparison of ACu values and the E½ values for metal reduction suggests that distortion towards tetrahedral symmetry and the presence of a soft donor atom like sulfur in porphyrins are required to generate spectral and electrochemical properties like those observed for the type I copper center in proteins.

  DOI：

  10.1039/a801934g
• 作为产物：
  描述：

  copper(II) choride dihydrate 、 5,10,15,20-tetraphenyl-21-oxaporphyrin 以 甲醇 、 氯仿 为溶剂， 反应 24.0h， 以100%的产率得到chloro-(5,10,15,20-tetraphenyl-21-oxaporphyrinato)copper(II)
  参考文献：
  名称：

  Molecular Structure, UV/Vis Spectra, and Cyclic Voltammograms of Mn(II), Co(II), and Zn(II) 5,10,15,20-Tetraphenyl-21-oxaporphyrins

  摘要：

  The 5,10,15,20-tetraphenyl-21-oxaporphyrin complexes of Mn(II), Co(II), and Zn(II) have been crystallized and studied by X-ray diffraction, NMR and UV/vis spectroscopy, and mass spectrometry as well as cyclic voltammetry. The X-ray structure of the earlier described Cu(II) complex is also reported. All complex structures possess a five-coordinate, approximately square-pyramidal geometry with a slight deviation of the heteroaromatic moieties from planarity. The packing structures are characterized by parallel strands of complex molecules interacting by weak hydrogen bonds. In the case of Zn(II) an octahedral complex has also been isolated using a side-chain hydroxy functionalized oxaporphyrin ligand; the structure was verified by NMR and EXAFS spectroscopy. Cyclic voltammetry studies reveal that the reduction of the complex bound Mn(II), Co(II), and Zn(II) ions is a ligand-centered process whereas the first oxidation step depends on the metal ion present.

  DOI：

  10.1021/ic302268h