2-ferrocenyl-4,6-diphenylpyrylium tetrachloroferrate | 1244549-83-4

• 英文名称: 2-ferrocenyl-4,6-diphenylpyrylium tetrachloroferrate
• CAS: 1244549-83-4
• 化学式: C₂₇H₂₁FeO*Cl₄Fe
• 分子量: 614.969
• InChiKey: NGKLDQKFBDSEOW-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2-ferrocenyl-4,6-diphenylpyrylium tetrachloroferrate 、 氨 以 水 为溶剂， 以57%的产率得到2-ferrocenyl-4,6-diphenylpyridine
  参考文献：
  名称：

  2-Ferrocenyl-substituted pyrylium ions from coupling of ethynylferrocene with cyclomanganated chalcones

  摘要：

  2-Ferrocenyl-substituted pyrylium salts are produced when orthomanganated chalcones are reacted with ethynylferrocene in CCl(4). When the reaction is carried out in benzene, intermediate ferrocenylsubstituted (eta(5)-pyranyl) Mn(CO)(3) species can be isolated which give the pyrylium cations on oxidation. The electrochemistry of the 2-ferrocenyl-pyrylium cations shows both oxidation (of the ferrocenyl) and reduction (of the pyrylium) processes, and the UV-visible spectra show a broad band at ca 680 nm which can be assigned to an intramolecular charge transfer transition. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.05.006
• 作为产物：
  描述：

  四氯化碳 、 二茂铁乙炔 、 [[1-phenyl-2-phenylcarbonyl-κO]ethenyl-κC(1)]tetracarbonylmanganese 以 四氯化碳 为溶剂， 以47%的产率得到2-ferrocenyl-4,6-diphenylpyrylium tetrachloroferrate
  参考文献：
  名称：

  2-Ferrocenyl-substituted pyrylium ions from coupling of ethynylferrocene with cyclomanganated chalcones

  摘要：

  2-Ferrocenyl-substituted pyrylium salts are produced when orthomanganated chalcones are reacted with ethynylferrocene in CCl(4). When the reaction is carried out in benzene, intermediate ferrocenylsubstituted (eta(5)-pyranyl) Mn(CO)(3) species can be isolated which give the pyrylium cations on oxidation. The electrochemistry of the 2-ferrocenyl-pyrylium cations shows both oxidation (of the ferrocenyl) and reduction (of the pyrylium) processes, and the UV-visible spectra show a broad band at ca 680 nm which can be assigned to an intramolecular charge transfer transition. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.05.006