| 189342-99-2

• CAS: 189342-99-2
• 化学式: C₄₄H₃₈As₂Cl₂N₃RuS
• 分子量: 962.691
• InChiKey: YAANMNRFFWUPFQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trichlorotris(triphenylarsine)ruthenium(III) 、 苯甲醛缩氨基硫 以 乙醇 、 苯 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Synthesis, Characterisation, Electrochemistry and Biological Activity of Ruthenium(III) Complexes Containing N.S Donor Ligands and Triphenylphosphine or Triphenylarsine

  摘要：

  Several new hexa-coordinated low-spin d(5) ruthenium(III) complexes of the type [RuX2(TSC)(EPh3)(2)] (where X=Cl or Br; H-TSC=benzaldehyde thiosemicarbazone, cinnamaldehyde thiosemicarbazone, thiophene-2-carboxaldehyde thiosemicarbazone and 2-furaldehyde thiosemicarbazone, E=P or As) have been synthesised by the reactions of [RuX3(EPh3)(3)] or [RuBr3(PPh3)(2)(MEOH)] with the various thiosemicarbazones. All the new complexes were characterised using various physico-chemical methods such as elemental analysis, spectral (IR, UV-VIS, EPR), magnetic moment and cyclic voltammetry data. In all these complexes, the thiosemicarbazones are bonded to the central ruthenium ion through the thiolato sulphur, after deprotonation, and the azomethine nitrogen. The antibacterial activity of some of the ligands and their complexes were also tested against two species of bacteria.

  DOI：

  10.1080/00945719708000213