fac-[Mn(CO)3(triphenylphosphino)(1,2-bis(diphenylphosphino)ethane)](BF4) | 247939-39-5

• 英文名称: fac-[Mn(CO)3(triphenylphosphino)(1,2-bis(diphenylphosphino)ethane)](BF4)
• CAS: 247939-39-5
• 化学式: BF₄*C₄₇H₃₉MnO₃P₃
• 分子量: 886.489
• InChiKey: ZHDLOQATEMDDKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三苯基膦 、 fac-Mn(CO)3(chloro)(1,2-bis(diphenylphosphino)ethane) 、 silver tetrafluoroborate 以 氯仿 为溶剂， 以99%的产率得到fac-[Mn(CO)3(triphenylphosphino)(1,2-bis(diphenylphosphino)ethane)](BF4)
  参考文献：
  名称：

  The preparation and reactions of the azides of fac-Mn(CO)3(P-P)N3. The X-ray crystal structures of fac-[Mn(CO)3(P-P)(OH2)]BF4, fac-Mn(CO)3(P-P)() [(P-P)=dppe and depe], and fac-[Mn(CO)3(depe)(PPh3)]BF4

  摘要：

  A simple three-step, high-yield synthesis of the titled azides from Mn-2(CO)(10) and P-P is described involving the intermediate aqua complexes, fac-[Mn(CO)(3)(P-P)(H2O)]BF4, 3a,b. The aqua ligand is very labile; it is easily exchanged for D2O, PPh3, and NO2-. Crystal structures of the two titled aqua complexes and fac-[Mn(CO)(3)(depe)(PPh3)]BF4, 6a, are reported. The aqua complexes react instantaneously with aqueous NaN3 to give quantitative yields of the corresponding covalent azides which undergo the expected 1,3-dipolar additions with CF3CN to give the corresponding tetrazoles whose crystal structures are also reported. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00161-8