[(C(C(Me)N(2,6-iPr2C6H3))2)AlMe(μ-O)]2Ti(benzyl)2 | 1041196-06-8

• 英文名称: [(C(C(Me)N(2,6-iPr2C6H3))2)AlMe(μ-O)]2Ti(benzyl)2
• CAS: 1041196-06-8
• 化学式: C₇₄H₁₀₂Al₂N₄O₂Ti
• 分子量: 1181.49
• InChiKey: WINCIBHVQCPLTA-BABQIKDXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [((2,6-(isopropyl)2C6H3)NC(CH3)CHC(CH3)N(2,6-(isopropyl)2C6H3))Al(methyl)OH] 、 tetrabenzyl titanium 以 甲苯 为溶剂， 生成 [(C(C(Me)N(2,6-iPr2C6H3))2)AlMe(μ-O)]2Ti(benzyl)2
  参考文献：
  名称：

  On the Quest for New Mixed-Metal μ-Oxo-bridged Complexes: Synthesis of Compounds Containing Transition Metal−Oxygen−Main Group Metal Motifs M−O−M¹ (M = Ti, Zr; M¹ = Al, Ga) without Cyclopentadienyl Ligands

  摘要：

  The reaction of TiBz(4) (Bz = benzyl) with LAlMe(OH), L = (2,6-iPr(2)C(6)H(3)NC(Me))(2)CH, afforded LAlMe(mu-O)TiBz(3) (1) and [LAlMe(mu-O)](2)TiBz(2) (2), whereas the corresponding reaction with ZrBz(4) resulted only in the formation of the trinuclear species [LAlMe(mu-O)](2)ZrBz(2) (3). The reaction of (MeS2Ga(OH))(2). THF (Mes = 2,4,6-Me3C6H2) with Ti(NEt2)(4) yielded the cluster compound TiGa6O7(NEt2)(2)(MeS)(6) (4). All compounds have been characterized by elemental analysis, NMR spectroscopy, and mass spectrometry. Additionally, single crystal X-ray structure data of 1, 3, and 4 are reported, Compounds 1-4 show low catalytic activities in the polymerization of ethylene. Revisiting known mu-oxo-bridged complexes containing the M-O-M-1 (M = Ti, Zr, Hf; M-1 = Al, Ga) skeleton revealed that the application of polynuclear group 13 hydroxides and oxo bridged complexes possesses a potential for the preparation of new polyoxometal clusters.

  DOI：

  10.1021/ic800567g