1,1’-bis-(N-piperidinyl)-ferrocenecarboxamide | 77773-43-4

• 英文名称: 1,1’-bis-(N-piperidinyl)-ferrocenecarboxamide
• 英文别名: 1,1'-bis(piperidino) ferrocenecarboxamide
• CAS: 77773-43-4
• 化学式: C₂₂H₂₈FeN₂O₂
• 分子量: 408.324
• InChiKey: FZWNNHIDNDJMIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  哌啶 、 1,1’-bis-ferrocene-di-(N-benzotriazolyl)carboxamide 以 甲苯 为溶剂， 反应 1.0h， 以58%的产率得到1,1’-bis-(N-piperidinyl)-ferrocenecarboxamide
  参考文献：
  名称：

  Ferrocenoyl Benzotriazole, IV: Microwave-Assisted Synthesis of Novel 1,1′-Bis-ferrocenamides

  摘要：

  An easily applicable microwave-assisted novel 1,1-bis-ferrocenoylbenzotriazole-mediated synthesis of novel derivatives for 1,1-bis-ferrocenamides was applied. This is a cheap, easy, and green method because of microwave irradiation and recovery of benzotriazole. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]

  DOI：

  10.1080/00397911.2013.797998

文献信息

• Aminocarbonylation of 1,1′-diiodoferrocene, two-step synthesis of heterodisubstituted ferrocene derivatives via homogeneous catalytic carbonylation/coupling reactions
  作者：Zsolt Szarka、Árpád Kuik、Rita Skoda-Földes、László Kollár

  DOI：10.1016/j.jorganchem.2004.05.046

  日期：2004.9

  Detailed investigation of the catalytic carbonylation of 1, 1'-diiodoferrocene has been carried out. The importance of the 1'-iodoferrocenecarboxamide- or 1'-iodo-ferroceneglyoxylic amide-type products as starting materials for the synthesis of various heterodisubstituted ferrocenes, that can serve as starting materials for ferrocene-based biosensors, was also proved. The potential of this reaction sequence was shown by the high-yielding synthesis of 1'-vinyl ferrocenecarboxamide/glyoxylic amide and 1'-acyl ferrocencarboxamide derivatives. (C) 2004 Elsevier B.V. All rights reserved.
• Yuan, Yao-Feng; Ye, Su-Ming; Zhang, Ling-Yun, Polyhedron, 1997, vol. 16, # 13, p. 2271 - 2277
  作者：Yuan, Yao-Feng、Ye, Su-Ming、Zhang, Ling-Yun、Wang, Ji-Tao、Wang, Hong-Gen

  DOI：——

  日期：——
• Fluxonial cryptands containing metallocene units
  作者：Phillip J. Hammond、Paul D. Beer、Clare Dudman、Ian P. Danks、C.Dennis Hall、John Knychala、Martin C. Grossel

  DOI：10.1016/s0022-328x(00)98998-8

  日期：1986.6