[Ni2Cl3(3,3-dihydro-2-methyl-2,4-bis[[((2,6-diisopropylphenyl)imino)ethyl]pyridin-2-yl]-1H-1,5-benzodiazepine)(H2O)2]Cl | 959588-49-9

• 英文名称: [Ni2Cl3(3,3-dihydro-2-methyl-2,4-bis[[((2,6-diisopropylphenyl)imino)ethyl]pyridin-2-yl]-1H-1,5-benzodiazepine)(H2O)2]Cl
• CAS: 959588-49-9
• 化学式: C₄₈H₆₀Cl₃N₆Ni₂O₂*Cl
• 分子量: 1012.24
• InChiKey: SZRZBZJSEJJZFK-UPYIFEPKSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 3,3-dihydro-2-methyl-2,4-bis((((2,6-diisopropylphenyl)imino)ethyl)pyridin-2-yl)-1H-1,5-benzodiazepine 以 乙醇 为溶剂， 以74%的产率得到[Ni2Cl3(3,3-dihydro-2-methyl-2,4-bis[[((2,6-diisopropylphenyl)imino)ethyl]pyridin-2-yl]-1H-1,5-benzodiazepine)(H2O)2]Cl
  参考文献：
  名称：

  Unsymmetric bimetal(II) complexes: Synthesis, structures and catalytic behaviors toward ethylene

  摘要：

  A series of unsymmetric bimetal(II) (Fe, Co and Ni) complexes ligated by 2-methyl-2,4-bis(6-iminopyridin-2-yl)-1H-1,5-benzodiazepines were synthesized and characterized by IR spectra and elemental analysis, while a representative nickel(II) complex (5a) was determined by single-crystal X-ray crystallography. These iron(II) complexes were found to exhibit good activities for ethylene oligomerization and polymerization in the presence of MMAO and afforded alpha-olefins in high selectivity, and the composition of oligomers followed the Schluz-Flory distribution. The nickel(II) complexes mainly dimerize ethylene with considerable activity. The influences of coordinative ligands and reaction parameters were fully investigated on the catalytic activity and properties of these complexes. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.08.020