[Au(μ-1-benzyl-2-imidazolyldiphenylphosphine)2][BF4] | 392233-45-3

• 英文名称: [Au(μ-1-benzyl-2-imidazolyldiphenylphosphine)2][BF4]
• 英文别名: [Au(1-benzyl-2-imidazolyl diphenylphosphine)2](BF4)
• CAS: 392233-45-3
• 化学式: BF₄*C₄₄H₃₈AuN₄P₂
• 分子量: 968.531
• InChiKey: FDGTWISRRXLCDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1-benzyl-2-imidazolyl)diphenylphosphine 、 [Au2(μ-1-benzyl-2-imidazolyldiphenylphosphine)2][BF4]2 以 乙腈 为溶剂， 以72.5%的产率得到[Au(μ-1-benzyl-2-imidazolyldiphenylphosphine)2][BF4]
  参考文献：
  名称：

  Solid state and solution investigations of derivatives of Group 11 metal ions with 1-benzyl-2-imidazolyldiphenylphosphine (L). Electrochemical behavior of [M2L3]2+ (M=CuI; AgI) and [AuL2]+ complexes

  摘要：

  The molecular crystal structure of (Bzim)Ph2P = L = 1-benzyl-2-imidazolyldiphenylphosphine (monoclinic; space group P2(1)/c # 14; a = 9.054(2), b = 9.394(3), c = 21.677(8) Angstrom; beta = 94.52(2)degrees; Z = 4) is reported here. This new P,N ligand reacts with Cu-1 or Ag-1 metal ions to give [M2L3](2+) dinuclear complexes where the bihapto ligand always bridges the metal centers. When L was added to [Au2L2](2+) complex the dinuclear gold cycle underwent a cleavage and the mononuclear species [AuL2](+) was obtained. The solution behavior of the complexes was investigated by H-1 and P-31 NMR at variable temperature, showing neither dissociative nor equilibrium reactions. The strong coordinating ability of the (Bzim)Ph2P ligand was also indicated by cyclic voltammetry investigation and the electrogenerated Ag(0) neutral complex, namely [Ag-2(mu-(Bzim)Ph2P)(3)], was detected as transient compound. The molecular crystal structure of [Cu-2(mu-(Bzim)Ph2P)(3)][BF4](2) is also reported (monoclinic; space group P2(1)/n # 14; a = 19.413(9), b = 19.81(1), c = 21.678(7) Angstrom; beta = 115.51(2)degrees; Z = 4). (C) 2001 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0020-1693(01)00582-5