[Rh(NBD)(C9H6(N(CH3)2)(P(CH(CH3)2)2))][BF4]*C4H8O | 540492-60-2

• 英文名称: [Rh(NBD)(C9H6(N(CH3)2)(P(CH(CH3)2)2))][BF4]*C4H8O
• 英文别名: [Rh(2,5-norbornadiene)(C9H6(N(CH3)2)(P(CH(CH3)2)2))][BF4]*C4H8O
• CAS: 540492-60-2
• 化学式: BF₄*C₄H₈O*C₂₄H₃₄NPRh
• 分子量: 629.331
• InChiKey: YSKFLXHXJIZPMY-CTJAPCTDSA-N

反应信息

• 作为产物：
  描述：

  silver tetrafluoroborate 、 RhCl(NBD)(C9H6(N(CH3)2)(P(CH(CH3)2)2)) 以 not given 为溶剂， 生成 [Rh(NBD)(C9H6(N(CH3)2)(P(CH(CH3)2)2))][BF4]*C4H8O
  参考文献：
  名称：

  A Catalytically Active, Charge-Neutral Rh(I) Zwitterion Featuring a P,N-Substituted “Naked” Indenide Ligand

  摘要：

  The synthesis and characterization of a new class of cationic and zwitterionic Rh(I) complexes, which feature multidentate ligands comprised of donor-functionalized indene or indenide units, are reported. This unusual new ligation strategy provides access to the first charge-neutral [kappa2-P,N]Rh(I) zwitterion, a complex that functions as a catalyst for the C-H/Si-H dehydrogenative coupling of styrene and triethylsilane.

  DOI：

  10.1021/ja034543v