acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate | 708277-40-1

• 英文名称: acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate
• CAS: 708277-40-1
• 化学式: C₃₃H₃₂AsNPRu*F₆P
• 分子量: 794.553
• InChiKey: MXZJMWZHSDRYPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate 、 [2-(二苯基胂基)乙基]二苯基膦 以 not given 为溶剂， 以0%的产率得到[((η5-cyclopentadienyl)Ru(acetonitrile)2)(μ-1-diphenylarsino-2-diphenylphosphinoethane)2](PF6)2
  参考文献：
  名称：

  Reaction of [CpRu(CH3CN)3]PF6 with bidentate ligands: structural characterization of [{CpRu(CH3CN)2}2(μ-η1:1-dppe)](PF6)2 [dppe=1,2-bis(diphenylphosphino)ethane]

  摘要：

  The reaction of [CpRu(CH3CN)(3)]PF6 with the bidentate ligands L-L = 1,2-bis(diphenylphosphino)ethane, dppe, and (1-diphenylarsino-2-diphenylphosphino)ethane, dpadppe, affords mononuclear or dinuclear complexes of formula [CpRu(eta(2)-L-L)(CH3CN)]PF6, [{CpRu(CH3CN)(2)}(2)(mu-eta(1:1)-L-L)](PF6)(2) and [{CpRu(CH3CN)}(2)(mu-eta(1:1)-L-L)(2)](PF6)(2) (L-L=dppe, dpadppe). All of the compounds are characterized by microarialysis and NMR [H-1 and P-31{H-1}] spectroscopy. The crystal structure of [{CpRu(CH3CN)(2)}(2)(mu-eta(1:1)-dppe)](PF6)(2) has been determined by X-ray diffraction analysis. The complex exhibits a dppe ligand bridging two CpRu(CH3CN)(2) fragments. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.02.035
• 作为产物：
  描述：

  [((η5-cyclopentadienyl)Ru(acetonitrile)2)(μ-1-diphenylarsino-2-diphenylphosphinoethane)2](PF6)2 以 二氯甲烷 为溶剂， 以0%的产率得到acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate
  参考文献：
  名称：

  Reaction of [CpRu(CH3CN)3]PF6 with bidentate ligands: structural characterization of [{CpRu(CH3CN)2}2(μ-η1:1-dppe)](PF6)2 [dppe=1,2-bis(diphenylphosphino)ethane]

  摘要：

  The reaction of [CpRu(CH3CN)(3)]PF6 with the bidentate ligands L-L = 1,2-bis(diphenylphosphino)ethane, dppe, and (1-diphenylarsino-2-diphenylphosphino)ethane, dpadppe, affords mononuclear or dinuclear complexes of formula [CpRu(eta(2)-L-L)(CH3CN)]PF6, [{CpRu(CH3CN)(2)}(2)(mu-eta(1:1)-L-L)](PF6)(2) and [{CpRu(CH3CN)}(2)(mu-eta(1:1)-L-L)(2)](PF6)(2) (L-L=dppe, dpadppe). All of the compounds are characterized by microarialysis and NMR [H-1 and P-31{H-1}] spectroscopy. The crystal structure of [{CpRu(CH3CN)(2)}(2)(mu-eta(1:1)-dppe)](PF6)(2) has been determined by X-ray diffraction analysis. The complex exhibits a dppe ligand bridging two CpRu(CH3CN)(2) fragments. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.02.035